From PS3 Developer wiki
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This is an example of an XMBML file
Add this query in category_video.xml in the position you want it to appear
And add this segments at the bottom
- Adding of Videos: BDISO from /dev_hdd0/BDISO/[name].iso, and DVDISO from /dev_hdd0/DVDISO/[name].iso
- After selecting in [videos]/[name.iso] must play through ps3 vidplayer